MENU

Rare-Earth-Free Magnets Explained

← Back to Functional Materials guides

TECHNOLOGY EXPLAINER

Rare-Earth-Free Magnets
— iron can supply the magnetization; what is short is anisotropy, and phases stable enough to be sintered

Between neodymium magnets and ferrite magnets there is a gap of about tenfold in maximum energy product (BH)max. Efforts continue to fill it with materials that use no rare earths (iron nitride Fe16N2, MnAl, tetrataenite L10-FeNi) and with materials that use fewer (Sm-Fe-N, higher-performance ferrite, and neodymium magnets with Ce and La substitution). This article explains why iron-based materials with high magnetization are still hard to turn into magnets, through three lenses: the balance between magnetization and magnetic anisotropy; metastable phases that cannot be sintered; and the fact that values for powders and thin films are not values for magnets. Company claims of practical use are kept apart as “not yet confirmed”, and laboratory powder values are not presented as the performance of production magnets.

Built from peer-reviewed papers (Engineering, J. Phys.: Condens. Matter, J. Appl. Phys., Sci. Rep., J. Phys. D, Phys. Rev. Mater., Adv. Mater., Mater. Trans., Crystals), a review article from Tohoku University (J. Jpn. Soc. Appl. Electromagnetics and Mechanics), manufacturers’ stated values, a Toyota announcement, and IEC and JIS catalogue pages / Checked 10 October 2026

Different magnet candidates are evaluated as separate specimens
Fig. 1 Conceptual image generated with ImageGen. Different magnet candidates are evaluated as separate specimens. Appearance and size do not establish magnetic strength or manufacturing readiness. Not actual facilities, products or measured results.
In this article
  1. What rare-earth-free magnets are (the short version)
  2. What is to be replaced — the size of the "gap"
  3. Design thinking — the balance of magnetization and anisotropy
  4. Where each candidate stands — iron nitride, MnAl, tetrataenite, Sm-Fe-N, ferrite, Ce/La substitution
  5. The wall of metastable phases — they cannot be sintered
  6. Powder values versus magnet values — how far coercivity has come
  7. How to read company claims
  8. Limits, and what could not be confirmed
  9. How to read evaluations and standards
  10. Glossary
  11. References (primary sources)
  12. Claim-to-source audit
How claims are labelled in this article

Sourced = stated in published material (link given)
Our calculation = a figure this article derived, with the assumptions spelled out
Not yet confirmed = a target, plan or preliminary estimate by a company or researchers, whose record has not been confirmed
Materials-design interpretations are marked separately as Commentary. Inference is shown in bold.

How to read the numbers in this article

Most numbers here are measurements on powders, thin films, small consolidated bodies or natural minerals, or theoretical calculations. The magnetization of a powder, or the “energy product” of a thin film, is not a value a magnet can deliver (Coey). Please do not read laboratory champion data as the performance of production products or of real operating conditions. Values for different sample forms are not set side by side to rank them. Company targets and plans are marked “not yet confirmed”, and no claim is made that one company or material is better than another. Prices and price forecasts are not covered.

1. What rare-earth-free magnets are (the short version)

  • The aim is the “gap”: the strongest neodymium magnet and the most widely used ferrite magnet are more than tenfold apart in ideal (BH)max, about 516 kJ/m³ and about 45 kJ/m³. A magnet that fills the middle is called a “gap magnet” and is the target for new materials without rare earths, but Coey says the search has met with limited successSourced [Source 1]
  • Iron-based materials have enough magnetization but not enough anisotropy: iron nitride and L10-FeNi can have magnetization as large as iron, yet the magnetic anisotropy that gives a magnet its resistance to a reverse field (coercivity) is smaller than in rare-earth compounds. There are also walls of stability and processing beyond the material’s propertiesSourced [Sources 1, 2, 5, 7]
  • A powder value is not a magnet value: for most candidates, coercivity at the powder, thin-film or small-body stage is only tens to about 200 kA/m, far from sintered neodymium (minimum HcJ of 955 kA/m or more)Sourced [Sources 6, 7, 9, 10, 17]
The single most important line

“Large magnetization” is only the entrance to being a magnet. To become a magnet a material needs enough anisotropy (κ above 1 for a magnet free of shape restrictions; about 0.5 or more even for shape-limited magnets), a phase stable enough to be consolidated without destroying it, and a microstructure that generates coercivitySourced [Source 1].

2. What is to be replaced — the size of the “gap”

Coey writes that the search for new, high-performance rare-earth-free magnet materials to bridge the wide gap between Nd2Fe14B (ideal (BH)max 515 kJ/m³) and BaFe12O19 (45 kJ/m³) has been less successful. As a price-performance criterion for a “gap magnet” he gives a cost of no more than about one dollar per joule of magnetic energySourced [Source 1]. Prices are not covered here; this article checks the distance in performance.

Material upper bound and magnet-level result, (BH)max in kJ/m³ Light bar = estimated upper bound of the material; dark bar = value reported for a magnet. Different forms and conditions. Sintered Nd2Fe14B reference point 516 406 Sm2Fe17N3 bonded magnets under 200 472 < 200 L10-FeNi (tetrataenite) no magnet value found > 335 none MnAl (tau phase) measured: cited in a paper ≈ 120 50 Sintered ferrite (Sr type) anisotropic products: 33-41.8 45.8 33–41.8 Fe16N2 (iron nitride) not confirmed here neither bound nor magnet value confirmed 0 100 200 300 400 500 Bounds: Nd2Fe14B and Sm2Fe17N3 from Coey Table 2 [Source 1]; L10-FeNi a preliminary estimate by Lewis et al. [Source 4]; MnAl from Arapan et al. [Source 11]; ferrite: (1/4)μ0Ms² = 45.8 kJ/m³ from Bs = 0.48 T (our calculation; the paper says 45) [Source 12]. Measured: N52 is Arnold’s typical value [Source 17]; Sm-Fe-N is Coey’s statement [Source 1]; ferrite is the range of commercial products in the review [Source 12].
Fig. 2 Drawing that includes our calculation (vector drawing). Estimated upper bound of (BH)max for each candidate (light bar) and the value reported for a magnet (dark bar). Bounds are literature values or our calculation; measured values are reports for different forms, so this is not a ranking and does not show magnet performance. Values are from [Sources 1, 4, 11, 12, 17].
Our calculation (1): the distance between the bound and reality

For a well-aligned magnet the upper bound of (BH)max is given from the saturation magnetization Ms as (1/4)μ0Ms² (Coey) [Source 1]. This article calculated the followingOur calculation.

  • Ferrite: from Bs = 0.48 T for Sr ferrite, 45.8 kJ/m³ (close to the theoretical value of 45 stated in the paper). The 33.0–41.8 kJ/m³ of commercial anisotropic ferrite is about 72–91% of that (33.0 / 45.8, 41.8 / 45.8) [Source 12]. Ferrite is already close to its own bound
  • MnAl: from Ms = 0.60 MA/m, about 113 kJ/m³ (consistent with the upper estimate of about 120 in the paper). The cited measured 50 kJ/m³ is about 44% of that [Source 11]
  • L10-FeNi: for μ0Ms = 1.6 T the bound is about 509 kJ/m³. The preliminary estimate of Lewis et al. (above 335 kJ/m³) is about 66% of it [Sources 4, 6]. No measured value for a magnet could be confirmed
  • Sm2Fe17N3: against an ideal of 472 kJ/m³, oriented bonded magnets are under 200 kJ/m³, under 42% (200 / 472) [Source 1]

Assumptions and limits: the bounds are ideal values for a well-aligned, fully dense body with the stated Ms, not values achievable in a magnet. The magnetization and anisotropy values for MnAl and FeNi vary between sources.

3. Design thinking — the balance of magnetization and anisotropy

Coey sorts the conditions for a usable magnet material with a hardness parameter κ, the square root of the ratio of anisotropy energy Ku to magnetostatic energy μ0Ms²: κ = (Ku / μ0Ms²)1/2. If κ is above 1, the material makes a magnet of any shape (hard). A κ of 0.1–1 is “semi-hard”, needing help from shape to reduce the demagnetizing field (bars, horseshoes), and a κ of about 0.5 or more makes a magnet possible. But the energy product of a semi-hard magnet stays at only about 10% of the idealSourced [Source 1].

Magnetization versus anisotropy: where the candidates sit (concept) x: μ0Ms (T); y: anisotropy constant (MJ/m³, log scale). Points are literature K1 values; Coey’s plot uses Ku with the dipole term, so positions differ slightly. 0 0.5 1 1.5 2 0.1 1 10 μ0Ms (T) Anisotropy (MJ/m³) κ = 1 above: any shape κ = 0.5 above: shape-limited Nd2Fe14B Sm2Fe17N3 SrFe12O19 (ferrite) L10-FeNi measured 0.2-0.93 analyses: 1.0-1.3 κ = (Ku/μ0Ms²)^(1/2). κ > 1 allows any shape; about 0.5 or more allows shape-limited magnets (Coey [Source 1]). Curves drawn by us from the formula. Values: Nd2Fe14B and Sm2Fe17N3 from Coey Table 2 (K1) [Source 1]; SrFe12O19 from Table 1 of Granados-Miralles et al. (0.35-0.36) [Source 12]; L10-FeNi from the table and text of Woodgate et al. (measured 0.2-0.93; analyses 1.0-1.3) and μ0Ms = 1.6 T from Goto et al. [Sources 5, 6].
Fig. 3 Concept diagram (vector drawing). An explanatory map of magnetization (μ0Ms) against anisotropy constant, with the positions of candidates and the κ = 1 and 0.5 lines. Points are literature K1 values; Coey’s plot uses Ku with the dipole term, so positions are not exactly the same. L10-FeNi is shown as a range because values vary widely between sources. Values are from [Sources 1, 5, 6, 12].

The map reads simply: further right means larger magnetization, higher up means larger anisotropy. Nd2Fe14B and Sm2Fe17N3 sit at the upper right with room to spare inside the κ > 1 region. Ferrite (SrFe12O19) has small magnetization (0.48 T) but enters the κ > 1 region through the balance with its anisotropy. L10-FeNi has large magnetization (1.6 T), but its anisotropy ranges from 0.2 to 1.0 MJ/m³ depending on the source, straddling the κ = 0.5 lineSourced [Sources 1, 5, 6, 12].

Our calculation (2): how far can Br go with iron nitride?

Ogawa’s review (Tohoku University) gives the anisotropy field of Fe16N2 powder as about 9.5 kOe (Our calculation about 756 kA/m) [Source 7]. The anisotropy field of Nd2Fe14B is 5.33 MA/m [Source 2], so this is about 14% of it (756 / 5,330). Coey says that even reaching a coercivity of 20–30% of the anisotropy field has usually taken many years of development [Source 1]. Applying that fraction to Fe16N2 gives a coercivity guide of about 150–230 kA/m (756 × 0.2, 756 × 0.3). Further, in a design using the (BH)max point, μ0HcJ at the operating temperature must exceed half of Br (Hirosawa et al.) [Source 2]. Read the other way, the upper limit of Br is 2μ0HcJ, which for a coercivity of 150–230 kA/m is about 0.4–0.6 T (2 × 4π × 10−7 × 150,000 to 230,000). That is about the same as the Br of sintered ferrite (380–400 mT in the Eclipse Magnetics datasheet) [Source 18].

Assumptions and limits: the fraction of 20–30% of the anisotropy field is a rule of thumb from rare-earth magnets, and there is no guarantee that it applies to iron nitride. The calculation assumes the working point is at the (BH)max point, and the coercivity needed changes with magnetic-circuit design (the load line). It is a rough estimate to illustrate that, even if the powder’s magnetization exceeds iron’s, the Br a magnet can use may be capped by the limit of anisotropy (coercivity); it is not a prediction of the performance of iron nitride magnets.

A materials engineer’s view 1: magnetization is set by the element, anisotropy by the structure

The size of magnetization is set mainly by the amount of 3d metals such as iron and cobalt. Strong uniaxial anisotropy, on the other hand, arises from the 4f electron orbitals of rare earths being biased in one direction within the crystal’s electric field (Hirosawa et al.) [Source 2]. For magnets made only of 3d metals with no rare earth, Kuz’min et al. say there is no general design rule for obtaining strong anisotropy [Source 3], so one must rely on “structural tricks”: lattice distortion and ordering (the nitrogen in iron nitride, the ordered stacking of L10).

In other words, going rare-earth-free is an attempt to have structure take over the anisotropy that rare earths used to carry. The structures that take over (metastable phases, ordered alloys) are weak to heat and impurities (Chapter 5). For a materials engineer, “a composition that earns magnetization”, “a structure that gives anisotropy” and “a process that keeps that structure” form a single design (commentary in this article).

4. Where each candidate stands — iron nitride, MnAl, tetrataenite, Sm-Fe-N, ferrite, Ce/La substitution

First, a summary table of the candidates. Each number carries the sample form (powder, thin film, consolidated body, natural mineral, theoretical calculation) and its conditions. Values for different forms are not ranked.

CandidateMain values (sample form, conditions)Where it stands (as confirmed)Main difficulty
α″-Fe16N2 (iron nitride)Powder: Ms 226 A·m²/kg (300 K; iron 218), K about 9.6×106 erg/cm³ (≈ 0.96 MJ/m³), Hk about 9.5 kOe [7]Powder synthesized reproducibly at the scale of tens of grams [7]. Coercivity of consolidated bodies up to 86.5–121 kA/m; no established value as a magnet [9, 10]A metastable phase that decomposes at about 200 °C [7]. Cannot be sintered. Critical single-domain size about 70 nm
τ-MnAl (including C-doped)Ms 0.60 MA/m, (BH)max 50 kJ/m³ (a measured value as cited), estimated upper bound about 120 kJ/m³ [11]Cheap elements, but Js is small and it is said to be unsuited to HEV and EV magnets [2]Metastable. Antiphase boundaries and twins lower coercivity and (BH)max [11]
L10-FeNi (tetrataenite)Js 1.6 T, Curie temperature 550 °C or above [6]. Anisotropy: measured 0.2–0.93 MJ/m³, calculated 0.23–0.78 [5]. Meteorite mineral: coercivity 95.5 kA/m, preliminary estimate of (BH)max above 335 kJ/m³ [4]Powder (NITE method): order parameter S = 0.71, coercivity 142 kA/m [6]The order-disorder transformation is at 200–320 °C and atomic diffusion is extremely slow. A highly ordered phase is hard to make [6]
Sm2Fe17N3 (Sm-Fe-N)TC 749 K, μ0Ms 1.54 T, K1 8.6 MJ/m³, ideal (BH)max 472 kJ/m³ [1]Sold as powder for bonded magnets. Oriented bonded magnets are under 200 kJ/m³ [1]Decomposes at about 600 °C and cannot be sintered. It uses Sm (not rare-earth-free, but free of Nd and heavy rare earths)
M-type ferrite (Sr type, higher performance)Bs 0.48 T, TC 473 °C, theoretical (BH)max about 45 kJ/m³. Commercial anisotropic products 33.0–41.8; La-Co substituted up to 44 kJ/m³ [12]The most produced magnet [12]. IEC 60404-8-1:2023 adds La-Co substituted ferrites [20]Sintering (1,100–1,350 °C) makes grains grow and coercivity falls [12]
Ce/La-substituted Nd-Fe-BToyota: up to 50% less Nd, no Tb or Dy, heat resistance equivalent to earlier magnets (company announcement) [15]A company announcement and a paper report. Status of practical use could not be confirmed [14, 15]La and Ce carry no magnetic moment in T-rich R-T compounds and contribute little to anisotropy [2]

All Sourced (source numbers in brackets in each cell). Values for different forms set side by side; not a ranking. Unit conversions: 1 emu/g = 1 A·m²/kg, 1 kOe = 79.577 kA/m.

(1) Iron nitride α″-Fe16N2 — high magnetization, too little anisotropy

Iron nitride is a metastable phase built from eight bcc iron cells with nitrogen placed at particular sites; the nitrogen makes the lattice tetragonal, and the c-axis becomes the easy axis. Its high saturation magnetization was proposed in 1972 for thin films (as Ogawa describes it)Sourced [Source 7]. Coey surveyed measurements on multiphase bulk samples and electronic-structure calculations and concluded that the average iron moment is in the range 2.3–2.6 μB near 0 K, and larger, about 2.9 μB, on the 4d sites that have no nitrogen neighbours [Source 8]. Ogawa showed by polarized neutron diffraction that the iron site farthest from nitrogen carries 2.6 ± 0.3 μB, larger than the 2.1–2.2 μB of bcc iron [Source 7].

To make a magnet, though, difficulties pile up. The powder Ogawa synthesized has a saturation magnetization above iron’s (226 versus 218 A·m²/kg at 300 K) and a magnetocrystalline anisotropy of about 0.96 MJ/m³ [Source 7], but in Coey’s classification iron nitride falls in the semi-hard group (κ below 1) [Source 1]. Hirosawa et al. also say that Fe16N2 particles face technical difficulties as a base for industrially useful bulk magnets [Source 2]. On consolidation, decomposition at about 200 °C rules out conventional sintering, so the focus is on bonded magnets made by low-temperature forming such as compression molding. Powder set in a magnetic field at a low fill fraction gave a squareness Mr/Ms of 0.80 and a coercivity of 2.5 kOe (about 199 kA/m), but at higher fill fractions c-axis alignment could not be confirmed even when set in fields of 20 kOe or more, says Ogawa [Source 7].

As an example of consolidated bodies, one study nitrided gas-atomized powder and consolidated it by spark plasma sintering (498–598 K, 40–80 MPa); at 548 K and 60 MPa it reports a density of about 80%, a saturation magnetization of about 230 A·m²/kg, a maximum coercivity of about 86.5 kA/m and an Mr/Ms of 0.42. The α″ phase is stable up to about 523 K, and above that decomposition into α-Fe and γ′-Fe4N proceeds [Source 9]. A route that nitrides a porous alloy made by leaching gave a coercivity of up to 121 kA/m, with a saturation magnetization smaller than iron’s [Source 10].

Ogawa holds that iron nitride will not fully replace rare-earth magnets, and points to partial replacement through nanocomposites with rare-earth magnets, and to the possibility of a new “high-magnetization, low-to-medium-coercivity” magnet that exceeds ferrite and alnico. For an unaligned, resin-bonded sample mixing iron nitride and Sm-Fe-N powders, the magnetization curve was intermediate between the two, suggesting strong magnetic interaction between the particles, resembling exchange coupling [Source 7].

(2) MnAl (τ phase) — cheap elements, and the wall of defects

τ-MnAl is a metastable ferromagnetic phase that appears when Mn is slightly above 50%; Mn and Al form an ordered L10 structure. Its magnetization is modest at 0.60 MA/m, its (BH)max is 50 kJ/m³ (a measured value as cited), and its estimated upper bound is about 120 kJ/m³. Because the raw materials are abundant and cheap, it is seen as a material to fill the niche between high-performance rare-earth magnets and general-purpose ferriteSourced [Source 11]. The microstructural problem is antiphase boundaries (APB) and twins. After the τ phase forms, coercivity is relatively low because of APBs, which make domain-wall nucleation easy. A granular structure containing fine twins and APBs can reduce (BH)max to only 5% of its theoretical maximum, the computational paper says, and it should be avoided in manufacturing [Source 11]. Hirosawa et al. say MnAl(C) has a small Js of about 0.7 T and drops out as a candidate for HEV and EV magnets [Source 2].

(3) Tetrataenite L10-FeNi — a material meteorites show, and that is hard to make

L10-FeNi is an ordered alloy in which iron and nickel atomic layers alternate, and it occurs naturally in iron meteorites that cooled extremely slowly. Goto et al. state a Js of 1.6 T (comparable to Nd-Fe-B), a Curie temperature of 550 °C or higher and a uniaxial anisotropy above 1×106 J/m³ (cited values) [Source 6]. Yet the anisotropy measured in experiments varies by source, 0.2–0.93 MJ/m³ in Woodgate et al.’s table; calculations give 0.23–0.78 MJ/m³, and some analyses suggest it could reach 1.0–1.3 MJ/m³. They attribute the discrepancy to the nanoscale polycrystalline, multivariant microstructure of the experimental samplesSourced [Source 5].

In measurements on tetrataenite from a meteorite (NWA 6259, composition about Fe55Ni44), the microstructure has three mutually orthogonal L10 variants that lower remanence; room-temperature coercivity was 95.5 kA/m, the Curie temperature at least 830 K, the anisotropy nearly temperature-independent, and a theoretical energy product possibly exceeding 335 kJ/m³ was suggested preliminarilyNot yet confirmed [Source 4]. The wall to synthesis is that the order-disorder transformation temperature is low, 200–320 °C, and below it atomic diffusion is extremely slow. Goto et al. inserted nitrogen to form FeNiN and then removed it (the NITE method), obtaining a single-phase powder of order parameter S = 0.71 without relying on diffusion, and raised coercivity from 14.5 kA/m (disordered phase) to 142 kA/m [Source 6].

(4) Sm-Fe-N — not rare-earth-free, but without Nd or heavy rare earths

Sm2Fe17N3 has intrinsic properties comparable to or better than Nd2Fe14B — Curie temperature 749 K, μ0Ms 1.54 T, K1 8.6 MJ/m³ — but it decomposes at about 600 °C and cannot be sinteredSourced [Source 1]. Coey says no oriented polymer-bonded magnet so far has exceeded 200 kJ/m³, about half the powder values. Melt-spun Sm-Fe-N powder has an energy product, taken as fully dense, of 164 kJ/m³, which exceeds the expectation for the isotropic case (a quarter of the ideal) thanks to the nanocrystals (about 15 nm on average) [Source 1]. The same paper notes that production is under 1% of Nd-Fe-B and that processing costs are high [Source 1]. IEC 60404-8-1:2023 adds isotropic REFeN bonded magnets [Source 20].

(5) Ferrite — already near its bound; the challenge is sintering

M-type ferrites (BaFe12O19, SrFe12O19) have a Bs of 0.48 T, a Curie temperature more than 150 °C higher than Nd2Fe14B, are chemically stable, and are the most produced magnet material. The (BH)max of commercial anisotropic magnets is 33.0–41.8 kJ/m³, La-Co substituted products reach up to 44 kJ/m³, and isotropic ones about 10 kJ/m³ (the theoretical value is about 45). Coercivity rises with temperature (in polycrystalline BaM, a maximum of about 380 kA/m near 250 °C) and then fallsSourced [Source 12]. The challenge is keeping coercivity through sintering. Powder coercivity is close to the single-crystal maximum (487–525 kA/m), but sintering at 1,100–1,350 °C makes grains grow, and in consolidated bodies the standard methods mostly give under 300 kA/m [Source 12]. A recent study reports that submicron particles of Ca-La-Co substituted Sr ferrite reached a coercivity of up to 7,880 Oe (about 627 kA/m) without loss of magnetization (71–72 emu/g)Sourced (a laboratory powder value, not a magnet value) [Source 13].

(6) Ce/La substitution — substitution to use “less rare earth”

There are attempts to replace part of the Nd with the more abundant, cheaper La and Ce. Coey says a lattice-matched mixture of La and Ce can be used for the substitution [Source 1], and Pathak et al. report that in Ce-and-Co co-doped alloys the intrinsic coercivity is the highest known for T ≥ 453 KSourced (a research report) [Source 14]. On 20 February 2018 Toyota announced a magnet that replaces part of the Nd with La and Ce, cuts Nd use by up to 50%, uses no Tb or Dy and keeps heat resistance equivalent to earlier neodymium magnets. It names three means: grain refinement to one tenth or less of conventional size, a two-layer grain structure with higher Nd concentration at the grain surface and lower in the core, and a specific ratio of La to CeSourced (company announcement) [Source 15]. The status of practical use was not checked here Not yet confirmed. Hirosawa et al. explain why La and Ce are hard: in T-rich R-T compounds they carry no magnetic moment and contribute little to anisotropy [Source 2]. For the same reason, in rare-earth-lean compounds such as the 1:12 (ThMn12) type, magnetic light rare earths such as Pr, Nd and Sm read as the promising choice [Source 2].

5. The wall of metastable phases — they cannot be sintered

Both neodymium and ferrite magnets become dense by pressing the powder to shape and firing it at high temperature. But many leading rare-earth-free candidates are metastable phases that break down at high temperature. Iron nitride decomposes into α-Fe and γ′-Fe4N at about 200 °CSourced [Source 7], and Sm-Fe-N decomposes at about 600 °C [Source 1]. L10-FeNi has an order-disorder transformation at 200–320 °C, and at temperatures where the ordered phase is stable the atoms barely move, so ordinary heat treatment does not raise the degree of order: it is a material that “cannot be made by waiting” [Source 6]. M-type ferrite, in contrast, is sintered at 1,100–1,350 °C [Source 12].

Metastable candidates cannot survive sintering temperatures (guide, °C) Blue = upper limit of stability; green = transformation range; orange = sintering temperature. Statements from different sources. α″-Fe16N2 (iron nitride) decomposes at about 200 °C ≈ 200 °C L10-FeNi (ordered alloy) order-disorder 200-320 °C 200–320 °C Sm2Fe17N3 (nitride) decomposes at about 600 °C ≈ 600 °C M-type ferrite (oxide) sintered at 1,100-1,350 °C 1,100–1,350 °C 0 200 400 600 800 1,000 1,200 1,400 Temperature (°C) Fe16N2: Ogawa (2024) [Source 7] (a spark-plasma sintering study reports stability up to about 523 K, 250 °C [Source 9]). FeNi: Goto et al. (2017) [Source 6]; Sm2Fe17N3: Coey [Source 1] and Hirosawa et al. [Source 2]; ferrite: Granados-Miralles et al. [Source 12]. Concept figure. The sintering temperature of NdFeB could not be confirmed from the sources used and is not shown.
Fig. 4 Concept diagram (vector drawing). The thermal limits of the candidates (upper limit of stability, transformation range) and the sintering temperature of ferrite, set along a temperature axis. Values come from sources that differ in measurement method and wording. Values are from [Sources 1, 2, 6, 7, 9, 12].

For iron nitride, ways to consolidate at low temperature are being explored in place of sintering. A body consolidated by spark plasma sintering (548 K) reached only about 80% of theoretical density [Source 9]. As Coey sets out, bonding lowers the share of magnetic powder, and when the powder is not aligned the ideal (BH)max falls further (an ideal 63 kJ/m³ for a random bonded magnet with a fill fraction of 0.7) [Source 1].

A materials engineer’s view 2: with metastable phases, consolidating without destroying them is harder than making them

The essence of these materials is that the synthesis temperature (low) and the consolidation temperature (high) do not match. Iron nitride is made by nitriding at low temperature, so raising the temperature to consolidate it makes it decompose. L10-FeNi is stable as an ordered phase only at low temperature, but at low temperature diffusion is too slow to make it. The NITE method worked because it avoided the slowness of diffusion: it first builds the ordered arrangement by inserting nitrogen, then removes only the nitrogen [Source 6].

Beyond this mismatch lies a contest of fill fraction and alignment. If sintering is not possible, the grains must be kept at single-domain size (about 70 nm for iron nitride), packed as densely as possible and aligned along the c-axis [Source 7]. Ogawa also points to the trade-off that smaller grains reduce the share of magnetic material that can be packed. In materials and process terms, powder size distribution, the surface oxide film (a non-magnetic coating), forming pressure, alignment in a field and low-temperature consolidation become design variables as important as the properties of the material itself (commentary in this article).

Powder handling and temperature-controlled processing are distinct
Fig. 5 Conceptual image generated with ImageGen. Powder handling and temperature-controlled processing are distinct. Metastable materials may transform at elevated temperatures; conventional sintering conditions are not automatically suitable. Not actual facilities, products or measured results.

6. Powder values versus magnet values — how far coercivity has come

Coey cautions about energy products reported for powders and thin films. For powders, a demagnetizing-field correction is applied and the curve is divided by the fill fraction to bring it to “full density”, so powder values are misleadingly optimistic and magnet values are closer to what an application can expect. A “thin-film permanent magnet”, he adds, is something of an oxymoron: a uniformly magnetized thin film produces almost no field outside, so its energy product is practically zeroSourced [Source 1].

How far coercivity has reached (kA/m; values under different conditions) Sample forms differ (powder, consolidated body, natural mineral). Not a ranking, and not magnet performance. Fe16N2 powder set in a field (low fill) Ogawa 2024: 2.5 kOe 199 Fe16N2 spark-plasma sintered body ~80% density, maximum 86.5 Fe16N2 sample from leaching route maximum 121 L10-FeNi powder (NITE, S = 0.71) disordered phase: 14.5 142 L10-FeNi from a meteorite room temperature 95.5 [Ref.] Sintered ferrite Y30H-1 HcJ 235-290 235–290 [Ref.] Sintered NdFeB N35 minimum HcJ 955 0 200 400 600 800 1000 example: 398 Dashed line: HcJ = 398 kA/m, applying the Hirosawa et al. condition (μ0HcJ above half of Br at the working point) to a magnet with Br = 1.0 T (an example, our calculation). The real condition applies at the operating temperature, so room-temperature HcJ must be higher. Sources: Ogawa [Source 7]; SPS body [Source 9]; leaching [Source 10]; Goto et al. [Source 6]; Lewis et al. [Source 4]; Eclipse [Source 18]; Arnold [Source 17].
Fig. 6 Drawing that includes our calculation (vector drawing). Reported coercivity of the candidates (powder, consolidated body, natural mineral), with sintered magnets (ferrite, neodymium) for reference. The dashed line is an example of the HcJ needed for a magnet with Br = 1.0 T used at its (BH)max point (398 kA/m, our calculation). Sample forms differ, so this is not a ranking and does not show magnet performance. Values are from [Sources 4, 6, 7, 9, 10, 17, 18].
Our calculation (3): an example of the coercivity needed

Our calculation Apply the condition of Hirosawa et al. (used at the (BH)max point, μ0HcJ at the operating temperature must exceed half of Br) [Source 2] to a magnet with Br = 1.0 T (an illustration). HcJ must then be about 398 kA/m or more (0.5 T / μ0). The reported values for iron nitride and L10-FeNi in Fig. 6 (86.5–199 kA/m) are about 20% to 50% of that (86.5 / 398 = 22%, 199 / 398 = 50%).

Assumptions and limits: Br = 1.0 T is an example for explanation. The coercivity actually needed is set by the magnetic circuit and the operating temperature (HcJ falls with temperature, so the room-temperature value must be higher still). Values for powders, consolidated bodies and natural minerals are not Br and HcJ of a magnet. The iron-nitride values are maxima from samples of different fill fraction, density and alignment.

A materials engineer’s view 3: raising coercivity tenfold is a job for microstructure more than for the material

Sintered ferrite (HcJ 235–290 kA/m, Eclipse Magnetics datasheet) [Source 18] has already reached the same range of coercivity as consolidated iron nitride and FeNi powder. But ferrite’s Br is small, so the coercivity it needs is small too: for a Br of 0.4 T the HcJ needed is Our calculation about 159 kA/m (0.2 T / μ0). For iron nitride and FeNi to become high-Br magnets, they must raise coercivity several-fold while keeping Br, and the tools for that are control of grain size, defects (the antiphase boundaries in MnAl) and grain boundaries (grain growth in ferrite sintering), as the examples of iron nitride, MnAl and ferrite in Chapter 4 show [Sources 11, 12].

Coey sorts the development of a new magnet material into four hurdles: (1) affordable ingredients, (2) useful intrinsic magnetic properties, (3) a microstructure that gives coercivity (harder the higher the magnetization), and (4) a route to industrial production. In permanent magnetism, he adds, there are no home runs [Source 1]. A materials engineer should ask not only about the intrinsic magnetic properties (hurdle 2) but how far hurdles 3 and 4 have been cleared (commentary in this article).

7. How to read company claims

Announcements of practical use by companies are read by keeping targets and plans apart from achievements. What could be confirmed in this article is as follows.

  • Toyota (announced 20 February 2018): a magnet that replaces part of the Nd with La and Ce, cutting Nd use by up to 50%, with no Tb or Dy. The announcement says the company will accelerate the development of mass-production technology and aim for early adoption in automobiles and robotics; the status of practical use could not be confirmedNot yet confirmed [Source 15]
  • Companies working to commercialize iron nitride magnets: an attempt was made to check Niron Magnetics’ public materials, but the domain assumed to be its official site (niromagnetics.com) could not be resolved from this working environment, so the company’s claims on production timing, performance and plant plans could not be confirmed and are not covered here
  • Moves in standardization: IEC 60404-8-1:2023 (4th edition) added hot-deformed REFeB magnets, HDDR REFeB bonded magnets, high-energy ferrites with La and Co substitution, and isotropic REFeN bonded magnets [Source 20]. No standard aimed at iron nitride, MnAl or L10-FeNi could be found (Chapter 9)
  • Export controls: China’s Ministry of Commerce Announcement No. 62 of 2025 (9 October 2025) made the technology for manufacturing Ce magnets, in addition to Sm-Co and Nd-Fe-B, a controlled “magnet manufacturing” technology, but it is suspended until 10 November 2026 under Announcement No. 70 (checked 10 October 2026)Sourced [Source 27]. The stages are set out in our explainer on permanent magnets and rare earths

Expressions such as “world first” or “groundbreaking” are treated as company or researcher claims; this article gives numbers only with conditions and only as far as the sources say.

8. Limits, and what could not be confirmed

(1) How far the sources were checked

For Kuz’min et al. [Source 3], Lewis et al. [Source 4], Coey (1994) [Source 8], the papers on consolidated iron nitride [Sources 9, 10], Pathak et al. [Source 14] and Cui et al. [Source 16], the publisher’s site could not be reached or the full text is not open, so only the abstract (as listed in a bibliographic database) was checked. The review by Cui et al. (Acta Materialia 158, 118–137) was not read in full, so its contents are not cited.

(2) Iron nitride values

The saturation magnetization of iron nitride is given in A·m²/kg and not converted to tesla, because the density could not be confirmed from a primary source. Company claims about iron nitride magnets (including Niron Magnetics) could not be confirmed. No measured (BH)max for Fe16N2 as a bulk magnet has been confirmed in the sources used.

(3) MnAl and FeNi values

The anisotropy constant of MnAl and the performance of commercial or prototype MnAl-C magnets could not be confirmed in the sources used. The anisotropy of L10-FeNi varies between sources (0.2–1.3 MJ/m³) and is shown here as a range. The estimate of (BH)max by Lewis et al. (above 335 kJ/m³) is preliminary.

(4) Assumptions in the calculations

The “upper limit of Br with iron nitride” in Chapter 3 and the “coercivity needed” in Chapter 6 are rough estimates that assume the rule of thumb for rare-earth magnets that coercivity is 20–30% of the anisotropy field, and a design that uses the (BH)max point. They are not predictions of the performance of iron nitride magnets.

(5) Out of scope

Alnico, cobalt nanowires, exchange-spring magnets, 1:12 thin films, computational screening of new compounds, prices and price forecasts, and the individual effects of additive elements are not covered. For the whole picture of permanent magnets see our explainer on permanent magnets and rare earths, for magnetocaloric materials see our explainer on magnetocaloric materials and magnetic refrigeration, and for magnetic thin-film materials see our explainer on spintronic materials.

Summary of this article
  • The aim is the gap between neodymium (bound about 516 kJ/m³) and ferrite (about 45 kJ/m³). Commercial ferrite already reaches about 72–91% of its own boundSourced / Our calculation
  • Magnetization can be earned from 3d metals, but anisotropy has to be taken over by structure. κ above 1 gives a magnet of any shape; about 0.5 or more allows shape-limited magnetsSourced
  • The candidates are metastable and cannot be sintered. Iron nitride decomposes at about 200 °C and Sm-Fe-N at about 600 °C, while L10-FeNi has a transformation at 200–320 °C and diffusion is too slow to make itSourced
  • Coercivity of powders and consolidated bodies stays at 86.5–199 kA/m. That is about 20–50% of the example coercivity (about 398 kA/m) needed at the working point of a magnet with Br = 1.0 TSourced / Our calculation
  • Keep company claims apart as targets and achievements. Toyota’s Ce/La substitution is a 2018 announcement whose practical use is unconfirmedNot yet confirmed

9. How to read evaluations and standards

The performance of rare-earth-free candidates divides into intrinsic magnetic properties (Ms, anisotropy, Hk, Curie temperature), first measured on powders or small samples by vibrating-sample magnetometry (VSM), SQUID, torque measurements, switching-field distribution and so on, and the hysteresis of consolidated samples (Br, HcJ, (BH)max). The performance of a magnet (Br, HcJ, (BH)max) is that measured, following a standard, on a sample whose whole volume can be regarded as homogeneous [Sources 19, 23].

Item evaluatedISOIEC / IEEEJISASTM (number and title only)What changes the value with measurement conditions
Demagnetization curve; Br, HcJ, (BH)max (closed circuit; sintered and bonded magnets)Could not be confirmedIEC 60404-5:2015 “Magnetic materials – Part 5: Permanent magnet (magnetically hard) materials – Methods of measurement of magnetic properties” (3rd edition) [19]
IEEE: could not be confirmed
JIS C 2501:2019 “Methods of test for permanent magnet” (MOD of IEC 60404-5:2015) [22]ASTM A977/A977M “Standard Test Method for Magnetic Properties of High-Coercivity Permanent Magnet Materials Using Hysteresigraphs” (edition seen: A977M-07, reapproved 2013) [25]Measurement temperature (JIS C 2501 recommends 23 ± 5 °C). Above an HcJ of 1.6 MA/m a closed circuit can give errors (note in JIS C 2500 [23]). For bonded magnets, fill fraction and alignment decide the value
Open-circuit measurement of high-coercivity magnets (superconducting magnet, demagnetizing-field correction)Could not be confirmedIEC 60404-18:2025 (1st edition, 2025-02-20) [21]. It targets magnets whose whole volume can be regarded as homogeneous, like the materials in IEC 60404-8-1JIS C 2500:2022 “Methods of measurement of the magnetic properties of permanent magnet (magnetically hard) materials in an open magnetic circuit using a superconducting magnet” [23]Could not be confirmedThe demagnetizing-field correction method changes the measured curve. For small samples and powders the effect of shape is large
Minimum values for material grades (ferrite, REFeN and REFeB bonded magnets, etc.)Could not be confirmedIEC 60404-8-1:2023 (4th edition, 2023-09-20). Adds hot-deformed REFeB, HDDR bonded, La-Co substituted ferrite and isotropic REFeN bonded [20]JIS C 2502:2019 “Materials for permanent magnet” (MOD of IEC 60404-8-1:2015) [24]ASTM A1054 “Standard Specification for Sintered Ferrite Permanent Magnets” (edition seen: A1054-16) [26]A specification’s minimum is a guaranteed value and differs from a maker’s typical value or a paper’s maximum. Only commercialized families are covered
Intrinsic properties of iron nitride, MnAl and L10-FeNi (candidates); magnetic measurement of powders and thin filmsCould not be confirmedNo applicable standard could be confirmedCould not be confirmedCould not be confirmedEach study differs in whether the sample is powder, thin film or consolidated body, in temperature, and in whether demagnetizing-field correction was applied. To compare reported values, confirm the sample form and the method

Standard numbers, titles and editions in each row are Sourced (checked on IEC, JSA and AFNOR catalogue pages and in the references of an Arnold technical note). Arranging the table is an editorial task of Our calculation. For ASTM standards, the ASTM site was not opened; only numbers and titles confirmed from non-ASTM public sources are given, and no test conditions, procedures or acceptance criteria are described. The texts of the standards are paid and were not checked.

How the positions differ: IEC 60404 is an international standard (TC 68), JIS C 2501 and C 2502 are national standards based on the 2015 editions of IEC 60404-5 and 60404-8-1 (MOD), and ASTM standards are US industry standards. All of them target commercialized magnet families (sintered neodymium, samarium-cobalt, ferrite, bonded magnets); no standard aimed directly at rare-earth-free candidate materials could be found.

Cautions when reading standards

  • A standard is a “test method”; it does not guarantee performance. The materials listed in a standard are already commercialized families. Even if a candidate’s number is written as “following the standard”, that does not make the material a grade in the standard
  • The same “coercivity” means different things for different sample forms. Powder coercivity, HcJ of a consolidated body and coercivity of a thin film carry different meaning as magnets even with the same number. Check how demagnetizing-field correction and fill fraction were handled
  • Values in research papers are neither standard values nor guaranteed values. Read them together with whether they are maximum, typical or minimum values, the temperature, and the number of samples

10. Glossary

Gap magnet
A magnet aimed at performance between neodymium and ferrite magnets.
κ (hardness parameter)
Square root of the ratio of anisotropy energy to magnetostatic energy. Above 1 gives a magnet of any shape.
Semi-hard
A material with κ of 0.1–1; needs shape to reduce the demagnetizing field.
Anisotropy field HA
The physical upper bound on the field needed to turn the magnetization.
Metastable phase
A phase that is not the most stable but persists kinetically. It decomposes or changes on heating.
Fe16N2 (iron nitride)
A metastable phase of iron and nitrogen only. Decomposes at about 200 °C.
τ-MnAl
A metastable ferromagnetic phase of Mn and Al (ordered L10 structure).
L10-FeNi (tetrataenite)
An alloy of Fe and Ni in ordered layers. Found naturally in meteorites.
Order parameter S
The degree of ordered arrangement. 1 for perfect order.
NITE method
Nitrogen insertion and topotactic extraction: build the ordered arrangement with nitrogen, then remove the nitrogen (a synthesis route for FeNi).
Antiphase boundary (APB)
A boundary where an ordered structure is shifted. Lowers coercivity in MnAl.
Nanocomposite magnet
A magnet combining a hard magnetic phase and a high-magnetization phase at the nanoscale.
REFeN
Compounds of rare earth, iron and nitrogen (such as Sm-Fe-N).

11. References (primary sources)

  1. Coey J. M. D. “Perspective and Prospects for Rare Earth Permanent Magnets”, Engineering 6, 119–131 (2020), DOI 10.1016/j.eng.2018.11.034 (open access) — doi.org/10.1016/j.eng.2018.11.034
  2. Hirosawa S., Nishino M., Miyashita S. (NIMS) “Perspectives for high-performance permanent magnets: applications, coercivity, and new materials”, Adv. Nat. Sci.: Nanosci. Nanotechnol. 8, 013002 (2017), DOI 10.1088/2043-6254/aa597c (open access) — doi.org/10.1088/2043-6254/aa597c
  3. Kuz’min M. D. et al. “Towards high-performance permanent magnets without rare earths”, J. Phys.: Condens. Matter 26, 064205 (2014), DOI 10.1088/0953-8984/26/6/064205 (abstract only checked) — doi.org/10.1088/0953-8984/26/6/064205
  4. Lewis L. H. et al. “Inspired by nature: investigating tetrataenite for permanent magnet applications”, J. Phys.: Condens. Matter 26, 064213 (2014), DOI 10.1088/0953-8984/26/6/064213 (abstract only checked) — doi.org/10.1088/0953-8984/26/6/064213
  5. Woodgate C. D. et al. “Revisiting Néel 60 years on: The magnetic anisotropy of L10 FeNi (tetrataenite)”, J. Appl. Phys. 134, 163905 (2023), DOI 10.1063/5.0169752 (full text of the preprint arXiv:2307.15470 checked) — doi.org/10.1063/5.0169752
  6. Goto S. et al. “Synthesis of single-phase L10-FeNi magnet powder by nitrogen insertion and topotactic extraction”, Sci. Rep. 7, 13216 (2017), DOI 10.1038/s41598-017-13562-2 (open access) — doi.org/10.1038/s41598-017-13562-2
  7. Ogawa T. (Tohoku University) “Rare-earth-free α″-Fe16N2 magnet and its applications”, J. Jpn. Soc. Appl. Electromagnetics and Mechanics 32(3), 524–528 (2024), DOI 10.14243/jsaem.32.524 (open access; in Japanese) — doi.org/10.14243/jsaem.32.524
  8. Coey J. M. D. “The magnetization of bulk α″Fe16N2 (invited)”, J. Appl. Phys. 76, 6632–6636 (1994), DOI 10.1063/1.358156 (abstract only checked) — doi.org/10.1063/1.358156
  9. Grigoras M. et al. “Microstructural and Magnetic Evolution of α″-Fe16N2 Bulk Magnets Consolidated by Spark Plasma Sintering”, Crystals 15(11), 969 (2025), DOI 10.3390/cryst15110969 (abstract only checked) — doi.org/10.3390/cryst15110969
  10. Kojima T. et al. “FeNi and Fe16N2 Magnets Prepared Using Leaching”, Mater. Trans. 60(6), 1066–1071 (2019), DOI 10.2320/matertrans.M2019019 (abstract only checked) — doi.org/10.2320/matertrans.M2019019
  11. Arapan S. et al. “Influence of antiphase boundary of the MnAl τ-phase on the energy product”, Phys. Rev. Mater. 3, 064412 (2019) (preprint arXiv:1903.06518 checked) — doi.org/10.1103/PhysRevMaterials.3.064412
  12. Granados-Miralles C., Jenuš P. “On the potential of hard ferrite ceramics for permanent magnet technology—a review on sintering strategies”, J. Phys. D: Appl. Phys. 54, 303001 (2021), DOI 10.1088/1361-6463/abfad4 (open access) — doi.org/10.1088/1361-6463/abfad4
  13. Lee J. et al. “Anisotropic characteristics and improved magnetic performance of Ca–La–Co-substituted strontium hexaferrite nanomagnets”, Sci. Rep. 10, 15929 (2020), DOI 10.1038/s41598-020-72608-0 (open access) — doi.org/10.1038/s41598-020-72608-0
  14. Pathak A. K. et al. “Cerium: An Unlikely Replacement of Dysprosium in High Performance Nd–Fe–B Permanent Magnets”, Adv. Mater. 27, 2663–2667 (2015), DOI 10.1002/adma.201404892 (abstract only checked) — doi.org/10.1002/adma.201404892
  15. Toyota Motor Corporation “Toyota Develops New Magnet for Electric Motors Aiming to Reduce Use of Critical Rare-Earth Element by up to 50%” (20 February 2018, news release) — global.toyota/en/newsroom/corporate/21139684.html
  16. Cui J. et al. “Current progress and future challenges in rare-earth-free permanent magnets”, Acta Mater. 158, 118–137 (2018), DOI 10.1016/j.actamat.2018.07.049 (abstract only checked) — doi.org/10.1016/j.actamat.2018.07.049
  17. Arnold Magnetic Technologies “Neodymium Iron Boron Magnet Catalog” (Rev. 210607) — arnoldmagnetics.com/…/Arnold-Neo-Catalog.pdf
  18. Eclipse Magnetics “Ferrite and ceramic magnets datasheet” (distributor datasheet) — eclipsemagnetics.com/…/ferrite_and_ceramic_datasheet.pdf
  19. IEC “IEC 60404-5:2015” product page (IEC Webstore) — webstore.iec.ch/en/publication/22142
  20. IEC “IEC 60404-8-1:2023” product page (IEC Webstore) — webstore.iec.ch/en/publication/68440
  21. IEC “IEC 60404-18:2025” product page (IEC Webstore) — webstore.iec.ch/en/publication/76495
  22. Japanese Standards Association (JSA) JIS C 2501:2019 “Methods of test for permanent magnet”, viewing preview (in Japanese) — webdesk.jsa.or.jp/preview/pre_jis_c_02501_000_000_2019_j_ed10_ch.pdf
  23. Japanese Standards Association (JSA) JIS C 2500:2022 “Methods of measurement of the magnetic properties of permanent magnet (magnetically hard) materials in an open magnetic circuit using a superconducting magnet”, viewing preview (in Japanese) — webdesk.jsa.or.jp/preview/pre_jis_c_02500_000_000_2022_j_ed10_ch.pdf
  24. Japanese Standards Association (JSA) JIS C 2502:2019 “Materials for permanent magnet”, viewing preview (in Japanese) — webdesk.jsa.or.jp/preview/pre_jis_c_02502_000_000_2019_j_ed10_ch.pdf
  25. Arnold Magnetic Technologies “What is the Magnetic Hysteresis Loop” (TECHNote TN 1501 rev.2015a; its reference list gives the number and title of ASTM A977M-07, reapproved 2013) — arnoldmagnetics.com/…/Tech-Notes_Hysteresis-Loop.pdf
  26. AFNOR “ASTM A1054-16” catalogue page (AFNOR Editions; not an ASTM site) — boutique.afnor.org/…/am95890/275610
  27. China, Ministry of Commerce Announcement No. 62 of 2025, decision on export controls on rare-earth technologies, 9 October 2025 (in Chinese) — mofcom.gov.cn/…/art_04a2df12…

12. Claim-to-source audit

Claim in the textBasisCategory
That the search for gap magnets between Nd2Fe14B (ideal 515 kJ/m³) and BaFe12O19 (45 kJ/m³) has been less successful; the price-performance criterion for a gap magnet (about one dollar per joule or less); the definition of κ and hard (κ above 1) and semi-hard (0.1–1, magnets possible at about 0.5 or more, energy product about 10% of ideal); iron nitride and L10-FeNi being semi-hard; the years needed to reach 20–30% of HA; the Sm2Fe17N3 values (TC 749 K, 1.54 T, K1 8.6 MJ/m³, (BH)max 472 kJ/m³, decomposition at about 600 °C, oriented bonded magnets under 200 kJ/m³ and about half the powder values, melt-spun powder 164 kJ/m³ with nanocrystals of about 15 nm, production under 1% of Nd-Fe-B); the Nd2Fe14B values (1.61 T, K1 4.3, (BH)max 516); cautions on powder and thin-film values; La/Ce substitution; the four hurdlesReview by Coey (2020)
Reference 1 https://doi.org/10.1016/j.eng.2018.11.034
Sourced
HA of Nd2Fe14B = 5.33 MA/m; the need for μ0HcJ to exceed half of Br at the operating temperature; MnAl(C) having a Js of about 0.7 T and dropping out as a candidate for HEV and EV; thin films and particles of Fe16N2, FeCo and L10-FeNi facing technical difficulties as a base for bulk magnets; rare earths (4f electrons) as the origin of anisotropy; La and Ce carrying no magnetic moment in T-rich R-T compoundsHirosawa et al. (2017, NIMS)
Reference 2 https://doi.org/10.1088/2043-6254/aa597c
Sourced
That there is no general design rule for strong anisotropy in 3d metals (abstract)Abstract of Kuz’min et al. (2014)
Reference 3 https://doi.org/10.1088/0953-8984/26/6/064205
Sourced
Meteoritic tetrataenite (NWA 6259, about Fe55Ni44): room-temperature coercivity 95.5 kA/m, Curie temperature of 830 K or more, three orthogonal variants lowering remanence, (BH)max possibly above 335 kJ/m³ (preliminary)Abstract of Lewis et al. (2014)
Reference 4 https://doi.org/10.1088/0953-8984/26/6/064213
Not yet confirmed
Anisotropy of L10-FeNi: measured 0.2–0.93 MJ/m³, calculated 0.23–0.78 MJ/m³, analyses suggesting 1.0–1.3 MJ/m³; the cause of the discrepancy (nanoscale polycrystalline, multivariant microstructure); Curie temperature of 830 K or moreWoodgate et al. (2023)
Reference 5 https://doi.org/10.1063/5.0169752
Sourced
L10-FeNi: Js 1.6 T, Curie temperature 550 °C or above, anisotropy above 1×106 J/m³ (cited value), order-disorder transformation at 200–320 °C, order parameter S = 0.71 by the NITE method, coercivity 14.5 → 142 kA/mGoto et al. (2017)
Reference 6 https://doi.org/10.1038/s41598-017-13562-2
Sourced
Fe16N2 powder: Ms 226 A·m²/kg (300 K; iron 218), K about 9.6×106 erg/cm³, Hk about 9.5 kOe, decomposition at about 200 °C, critical single-domain size about 70 nm, moments by iron site (2.6 ± 0.3 μB), Mr/Ms 0.80 and coercivity 2.5 kOe for powder set in a field at low fill fraction, no alignment confirmed at high fill fraction, nanocomposite with Sm-Fe-N, synthesis at the scale of tens of gramsOgawa (2024, Tohoku University)
Reference 7 https://doi.org/10.14243/jsaem.32.524
Sourced
Average iron moment of 2.3–2.6 μB and about 2.9 μB on the 4d sites with no nitrogen neighboursAbstract of Coey (1994)
Reference 8 https://doi.org/10.1063/1.358156
Sourced
Spark-plasma-sintered Fe16N2 (548 K, 60 MPa, density about 80%, about 230 A·m²/kg, maximum coercivity 86.5 kA/m, Mr/Ms 0.42, α″ phase stable up to about 523 K)Abstract of Grigoras et al. (2025)
Reference 9 https://doi.org/10.3390/cryst15110969
Sourced
Fe16N2 by the leaching route: coercivity up to 121 kA/m, saturation magnetization smaller than iron’s, no L10-FeNi phase confirmedAbstract of Kojima et al. (2019)
Reference 10 https://doi.org/10.2320/matertrans.M2019019
Sourced
τ-MnAl: Ms 0.60 MA/m, (BH)max 50 kJ/m³ (cited), estimated upper bound about 120 kJ/m³, metastable, lowered coercivity from APBs and twins, (BH)max possibly falling to 5% of theory with fine twins and APBsArapan et al. (2019)
Reference 11 https://doi.org/10.1103/PhysRevMaterials.3.064412
Sourced
M-type ferrite: Bs 0.48 T, TC 473 °C, K1 0.35–0.36 MJ/m³, theoretical (BH)max about 45 kJ/m³, commercial anisotropic products 33.0–41.8 kJ/m³, La-Co products up to 44, isotropic about 10, temperature dependence of coercivity, sintering at 1,100–1,350 °C and the fall in coercivity from grain growth (under 300 kA/m), the most produced magnet materialGranados-Miralles and Jenuš (2021)
Reference 12 https://doi.org/10.1088/1361-6463/abfad4
Sourced
Submicron Ca-La-Co substituted Sr ferrite particles: coercivity up to 7,880 Oe (about 627 kA/m) with magnetization of 71–72 emu/g keptLee et al. (2020)
Reference 13 https://doi.org/10.1038/s41598-020-72608-0
Sourced
In Ce-and-Co co-doped Nd-Fe-B, the highest intrinsic coercivity known for T ≥ 453 K (as reported in the paper)Abstract of Pathak et al. (2015)
Reference 14 https://doi.org/10.1002/adma.201404892
Sourced
Toyota’s Ce/La-substituted magnet (announced 20 February 2018: up to 50% less Nd, no Tb or Dy, three technologies) and the aim of early adoption. Status of practical use not checkedToyota news release (company announcement and target)
Reference 15 https://global.toyota/en/newsroom/corporate/21139684.html
Not yet confirmed
The existence of a review of rare-earth-free magnets, and the goal for non-rare-earth magnets of filling the gap (abstract only; the full text is not cited)Abstract of Cui et al. (2018)
Reference 16 https://doi.org/10.1016/j.actamat.2018.07.049
Sourced
Sintered neodymium N52 (typical (BH)max 406 kJ/m³) and the minimum HcJ of N35 of 955 kA/mArnold catalog (Rev. 210607)
Reference 17 https://www.arnoldmagnetics.com/wp-content/uploads/2019/06/Arnold-Neo-Catalog.pdf
Sourced
Sintered ferrite Y30H-1: Br 380–400 mT, Hcj 235–290 kA/m (distributor datasheet)Eclipse Magnetics
Reference 18 https://www.eclipsemagnetics.com/site/assets/files/22199/eclipsemagnetics_ferrite_and_ceramic_datasheet.pdf
Sourced
Standards: IEC 60404-5:2015, IEC 60404-8-1:2023 (4th edition, added materials), IEC 60404-18:2025IEC Webstore
Reference 19 https://webstore.iec.ch/en/publication/22142
Reference 20 https://webstore.iec.ch/en/publication/68440
Reference 21 https://webstore.iec.ch/en/publication/76495
Sourced
Standards: JIS C 2501:2019, JIS C 2500:2022 (closed-circuit error above HcJ of 1.6 MA/m), JIS C 2502:2019JSA viewing previews
Reference 22 https://webdesk.jsa.or.jp/preview/pre_jis_c_02501_000_000_2019_j_ed10_ch.pdf
Reference 23 https://webdesk.jsa.or.jp/preview/pre_jis_c_02500_000_000_2022_j_ed10_ch.pdf
Reference 24 https://webdesk.jsa.or.jp/preview/pre_jis_c_02502_000_000_2019_j_ed10_ch.pdf
Sourced
Standards: ASTM A977M-07 (title) and ASTM A1054-16 (title and description of scope). The ASTM site was not opened; confirmed from an Arnold reference list and an AFNOR catalogue pageArnold TN 1501, AFNOR Editions
Reference 25 https://www.arnoldmagnetics.com/wp-content/uploads/2017/10/FINAL_Tech-Library_Tech-Notes_Hysteresis-Loop.pdf
Reference 26 https://www.boutique.afnor.org/en-gb/standard/astm-a105416/standard-specification-for-sintered-ferrite-permanent-magnets/am95890/275610
Sourced
In MOFCOM Announcement No. 62 of 2025, “magnet manufacturing” means technology for making Sm-Co, Nd-Fe-B and Ce magnets; suspended until 10 November 2026 by Announcement No. 70Announcement of MOFCOM
Reference 27 https://www.mofcom.gov.cn/zcfb/blgg/gg/2025/art/2025/art_04a2df12aa7c4529be797fd70eaf0dc8.html
Sourced
The distance between bound and measured value (ferrite 72–91% of about 45.8 kJ/m³, MnAl about 44% of about 113 kJ/m³, FeNi about 66% of about 509 kJ/m³, Sm2Fe17N3 under 42%); the anisotropy field of Fe16N2 at about 14% of that of Nd2Fe14B; the coercivity guide of 150–230 kA/m and the upper limit of Br of 0.4–0.6 T; HcJ of 398 kA/m for a magnet with Br = 1.0 T and its ratio to the values in Fig. 6 (22–50%); HcJ of about 159 kA/m for a magnet with Br of 0.4 TOur calculation. Assumes (1/4)μ0Ms², the ratio of HcJ to HA (Coey’s 20–30%) and μ0HcJ above Br/2 (Hirosawa et al.). Real values differ with magnetic circuit, operating temperature and sample. Not a prediction of iron nitride magnet performanceOur calculation
Tesla conversion of iron-nitride magnetization; measured (BH)max of bulk Fe16N2 magnets; the anisotropy constant of MnAl and the performance of MnAl-C magnets; company claims on iron-nitride magnets (including Niron Magnetics); alnico, cobalt nanowires and 1:12 thin films; prices; the sintering temperature of sintered neodymiumCould not be confirmed in the primary sources reachable for this article, or not covered by this article’s policy, and so not statedCommentary
The readings “magnetization is set by the element, anisotropy by the structure”, “with metastable phases, consolidating without destroying them is harder than making them” and “raising coercivity tenfold is a job for microstructure”; and the framing of rare-earth-free as an attempt to have structure take over the anisotropyThis article’s own arrangement and interpretation of published material; not views stated by any company or bodyCommentary
That Figs. 2 to 4 and 6 are explanatory drawings, not measured figures or real data, and that Figs. 1 and 5 are AI-generated imagesNote from this articleCommentary

Last updated 10 October 2026. Sources are limited to primary material (peer-reviewed papers, a review article from Tohoku University, manufacturers’ stated values, a Toyota announcement, an announcement of China’s Ministry of Commerce, and standards-body catalogue pages). The texts of standards are paid and were not checked. The ASTM International site was not opened, because that body states that AI use of the site is not permitted. For some papers (Kuz’min et al., Lewis et al., Coey 1994, the papers on consolidated iron nitride, Pathak et al. and Cui et al.) only the abstract was checked. Because the article includes values for powders, thin films, small consolidated bodies and natural minerals, and theoretical calculations, please do not read them as magnet performance or as values for production products. Structural readings and materials-design interpretations are marked as Commentary and kept separate from sourced fact. Company claims on iron-nitride magnets (including Niron Magnetics), the measured (BH)max of bulk Fe16N2 magnets, the anisotropy constant of MnAl and the status of practical use of Toyota’s magnet could not be confirmed and are not stated here. All figures are explanatory concept graphics. Figs. 2 to 4 and 6 are vector drawings; Figs. 1 and 5 are AI-generated images, and none of them shows a real micrograph or physical product.

🌐 Japanese