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Electrolyzer Durability Data: Interpreting Hours and Degradation

HydroXpand USA
Overview
Operating hours in durability reports often reflect test duration rather than actual stack lifetime. To accurately assess performance, engineers must evaluate degradation rates (µV/h) alongside specific operating conditions and end-of-life criteria.
In Depth

Key Findings

Operating hours reported in durability data typically indicate how long a stack was tested, not its total lifespan. A number such as 2,000, 5,000, or 10,000 hours does not inherently reveal if a cell remained healthy or reached its limit. To determine actual lifetime, an end-of-life criterion—the maximum allowable voltage rise—must be established, though this is often not documented by suppliers.

Technical Details

Degradation rate, measured in microvolts per hour (µV/h) per cell, allows for the comparison of runs with different lengths. When analyzing these rates, three factors are critical:

  • Unit Scale: Rates can be expressed per cell or per stack; for a 23-cell stack, 20 µV/h per cell equals 0.46 mV/h for the whole stack.
  • Fitting Window: Including the initial settling period increases the calculated rate compared to fitting only the later, stable part of the run.
  • Current Stability: Rates are normally calculated at a fixed current; changing loads cannot be reduced to a rate in the same manner.

Furthermore, hours may be continuous or cumulative, with the latter including shutdowns and restarts that add specific loads to the cell.

Background & Context

Durability is heavily influenced by current density, temperature, electrolyte concentration, and outlet pressure. For example, a published AEM run reached 8,900 hours at 0.2 A/cm², starting at 1.92 V with a rise of 18 µV/h. In contrast, a two-cell, 16 cm² short stack using an HXP-an anode and a PiperION 80 µm membrane ran for 6,358 hours at a higher current density of 0.625 A/cm², with voltage rising from 1.893 V to 1.979 V.

Significance & Outlook

Component synergy is vital; the same anode in the aforementioned short-stack test yielded only 1,234 hours when paired with a different membrane. This demonstrates that durability figures for a single electrode cannot be transferred to different cell configurations. Currently, the HXS-2 2 kW stack has achieved over 3,000 hours of cumulative operation at 0.3 M KOH, 40 °C, and 50 A.

Source: https://hydroxpand.com/en/blog/2026-10-08-reading-electrolyzer-durability-data/

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